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Here, a family of benzene-1,3,5-tricarboxamide (BTA) derivatives that comprise a BTA moiety connected to an amphiphilic chain is synthesised with the aim to elucidate the role of hydrophobic and hydrogen-bonding interactions in the self-assembly of these BTAs.

Understanding the self-assembly of small molecules in water is crucial for the development of responsive, biocompatible soft materials. The results show that an undecyl spacer is the minimum length required for these BTAs to self-assemble into supramolecular polymers.

Here, a family of benzene-1,3,5-tricarboxamide (BTA) derivatives that comprise a BTA moiety connected to an amphiphilic chain is synthesised with the aim to elucidate the role of hydrophobic and hydrogen-bonding interactions in the self-assembly of these BTAs. Interestingly, exchange studies reveal only minor differences in exchange rates between BTAs containing undecyl or dodecyl spacers.

TY - JOURT1 - Supramolecular polymerisation in water; Elucidating the role of hydrophobic and hydrogen-bond interactions AU - Leenders, C.

The amphiphilic chain consists of an alkyl chain with a length of 10, 11, or 12 methylene units, connected to a tetraethylene glycol (at the periphery).

Cells possess a myriad of DNA maintanance pathways that ensure genome stability.

In recent years, it has been reported that members of the Primase-Polymerase (Prim-Pol) family play crucial roles in repairing and tolerating DNA damage in cells.

The results show that an undecyl spacer is the minimum length required for these BTAs to self-assemble into supramolecular polymers.

PY - 2016Y1 - 2016N2 - Understanding the self-assembly of small molecules in water is crucial for the development of responsive, biocompatible soft materials.

Principal Supervisor: Rui Monteiro, Institute of Cancer and Genomic Sciences, College of Medical and Dental Sciences Co-supervisor: Professor Ferenc Mueller, Institute of Cancer and Genomic Sciences, College of Medical and Dental Sciences Ph D project title: Elucidating the role of cis- and trans- regulation of transcription in the formation of blood stem cells University of Registration: University of Birmingham Project outline: Background Haematopoietic stem cells (HSCs) arise from specialized haemogenic endothelial cells located in the floor of the embryonic dorsal aorta, the haemogenic endothelium (HE).

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